Last edited 13 Jun 2019

Silicon

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[edit] Introduction

Silicon (chemical symbol Si) is a naturally occurring, non-metallic element and, after oxygen, is the second most abundant element in the earth’s crust, found mainly as silica in sand. Silicates are the chief constituents of many rocks, clays and soils and make up more than 90% of the Earth’s crust.

Hard and brittle, silicon has a crystalline structure and a metallic blue-grey lustre. Because it is classed as ‘metalloid’, it displays properties of both metals and non-metals.

Silicon has an affinity for oxygen and so is rarely found in its pure elemental form but as silicon dioxide (SiO2 or silica). Silica occurs in 12 different crystal modifications which include alpha quartz, a main constituent of granite and sandstone, rock crystal, rose quartz, smoky quartz, morion, amethyst and citrine. Also, as agate, onyx, jasper and flint.

Commercially, silicon is used mostly without processing in semiconductors, and is essential to integrated circuits. Its high conductivity also sees its use in solar power cells. But its main use is in steel refining, aluminium casting and chemicals. Silicon of up to 99% purity can be made using an electric arc furnace by reducing quartzite or sand with high-purity coke

[edit] Uses in construction

Many construction materials contain silica e.g asphalt, brick, cement, concrete, plasterboard, grout, mortar, tile and stone. It is also used as a filler in some plastics and is added to white ceramic ware such as porcelain and to some types of glass.

Silicates are used in the production of Portland cement for concrete, mortar and stucco, and also form the basis for the widely-used synthetic polymers called silicones. Silicates are also constituents of optical fibres, fibreglass and glass wool for thermal insulation.

Silicon resins are used in the construction industry as additions to coatings to which they impart resistance to heat, oils, salts, acids, and alkalis. Because they also provide water repellence, they are used in water repellent treatments for brickwork and masonry.

Silicon is also added to polishes, mechanical seals, high temperature greases and waxes, caulking compounds, breast implants, contact lenses, explosives and fireworks. Also, to hi-tech abrasives, hi-strength ceramics and in super alloys.

[edit] Silicone rubber

Silicone rubber is a synthetic rubber. Compared to natural rubber, it has better resistance to high and low temperatures.

[edit] Silicon carbide

This is used as an abrasive to smooth a variety of materials. It is formed when carbon and sand (or silica) are heated together in a furnace. It may be marketed under the trade name of ‘carborundum’.

[edit] Silicosis

Exposure to silica dust can pose a major health hazard and lead to silicosis of the lung or ‘pneumonoultramicroscopicsilicovolcanoconiosis’. It is a long-term disease usually caused by inhaling large amounts of crystalline silica dust, typically over many years.

The Health & Safety Executive’s ‘Control of Exposure to Silica Dust’ advises that when cutting, sanding or carving materials containing silica, a fine dust (Respirable Crystalline Silica (RCS)) is created that may get into the lungs. RCS is too fine to see under normal lighting conditions.

Typical activities that may generate RCS include:

[edit] Silicon, silicone and silica

Differentiating between silicon, silicone and silica

  • Silicon is a naturally occurring element
  • Silicone is a man-made polymer that is derived from silicon, a class of silicon-based chemical compounds used in paints, adhesives, lubricants and breast implants, among other applications
  • Silica is another name for silicon dioxide (SiO2).

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