Last edited 05 May 2019

PTFE

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The Millennium Dome, London, comprises a double-layer PTFE-coated glass-fabric membrane.

Contents

[edit] Introduction

Polytetrafluoroethylene (PTFE) is a thermoplastic compound noted for its very significant chemical inertness and heat resistance. Commonly encountered as a non-stick coating for pots and pans it is sometimes referred to by the trade name ‘Teflon’ or 'Syncolon'. It is widely used for a variety of engineering and chemical applications.

[edit] Properties of PTFE

PTFE is a synthetic fluoropolymer of tetrafluoroethylene discovered accidentally by Dr Roy Plunkett in 1938 while working for DuPont in the US. With a high molecular weight, it consists entirely of carbon and fluorine. Displaying reduced stress cracking and corrosion, it is also hydrophobic, which means it cannot be wetted by water or water-containing liquids. It also displays one of the lowest coefficients of friction of any solid so that even geckos and insects cannot crawl up it.

Its properties include:

  • Very low friction coefficient.
  • Resists corrosion.
  • Significantly chemically inert.
  • Withstands wide temperature ranges.
  • Good abrasion resistance.
  • Non-porous.

[edit] Uses in construction

Generally in construction and infrastructure, PTFE’s main applications are for providing friction-control performance wherever components move in relation to one another e.g in the fabrication and erection of steelwork to minimise the stresses produced by the imperfect alignment of steel members; for expansion joints, slide bearings, on bridge bearings and dams, gaskets and electrical insulation; also, as an insulator to prevent thermal bridging e.g where a pipe passes through an external wall.

As a lubricant, it reduces friction, wear and energy consumption (in machinery). This was exploited skilfully on the construction of the Millau Viaduct in southern France: PTFE-coated bearings were used to reduce the huge friction generated as the road deck was slid into place over the supporting pylons.

In 1972, PTFE-coated glass fabrics were introduced following their development by NASA for the manufacture of space suits. The Millennium Dome in London, comprises a double-layer PTFE-coated glass fabric membrane.

PTFE-coated glass is expensive but tends to have a longer life than PVC coated polyester, it is also stronger, adn self-cleaning. The first application of PTFE-coated glass was in the La Verne College Student Centre, in California (1973). In 1993, twenty years later, the original membrane was still in place, and was still capable of withstanding around 75% of its original design load.

Other developments have included woven PTFE fibre (hydrophobic, microporous, and extremely durable) for tensile structures.

For more information see: Fabric structures.

Wiring in aerospace and computer applications consumes about 50% of PTFE production, particularly as an insulator in connectors and cables. Other uses include gears, seals, gaskets and bushings, lining hose assemblies, windscreen wiper blades, industrial pipe lines, and as a waterproof coating for outdoor clothing.

PTFE is closely related to ETFE (ethylene-tetra-fluoro-ethylene) which comprises modified copolymers of ethylene and tetrafluoroethylene. It has many similar properties to PTFE and in recent years has been widely used in construction.

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